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A phosphor is a substance that exhibits the phenomenon of phosphorescence (sustained glowing after exposure to oxygen or energized particles such as electrons). Monochrome monitors are a type of computer display which were very common in the early days of computing from the 1960s through the 1980s before the color monitors became popular An optical phenomenon is any observable event which results from the interaction of Light and Matter. Phosphorescence is a specific type of Photoluminescence related to fluorescence. The electron is a fundamental Subatomic particle that was identified and assigned the negative charge in 1897 by J

The chemical element phosphorus (Greek. Phosphorus, (ˈfɒsfərəs is the Chemical element that has the symbol P and Atomic number 15 Greek (el ελληνική γλώσσα or simply el ελληνικά — "Hellenic" is an Indo-European language, spoken today by 15-22 million people mainly phosphoros, meaning "light bearer") was discovered by German alchemist Hennig Brand in 1669. Germany, officially the Federal Republic of Germany ( ˈbʊndəsʁepuˌbliːk ˈdɔʏtʃlant is a Country in Central Europe. Hennig Brand(t (c 1630 – c 1710) was a merchant and amateur alchemist in Hamburg Germany who discovered Phosphorus around 1669 Working in Hamburg, Brand attempted to distill some kind of "life essence" from his urine, and in the process produced a white material that glowed in the dark. Hamburg (English, German: ˈhambʊɐk local pronunciation Low German / Low Saxon: Hamborg) is the second-largest city in Germany Since that time, the term phosphorescence has been used to describe substances that shine in the dark without burning.

Phosphorus itself is not a phosphor; it is highly reactive and gives-off a faint chemiluminescent glow upon uniting with oxygen. Chemiluminescence (sometimes " chemoluminescence " is the emission of Light ( Luminescence) with limited emission of heat as the result of a chemical Oxygen (from the Greek roots ὀξύς (oxys (acid literally "sharp" from the taste of acids and -γενής (-genēs (producer literally begetteris the The glow observed by Brand was actually caused by the very slow burning of the phosphorus, but as he saw no flame nor felt any heat he did not recognize it as burning.

Phosphors are transition metal compounds or rare earth compounds of various types. In Chemistry, the term transition metal (sometimes also called a transition element) has two possible meanings It commonly refers to any element in Rare earth elements and rare earth metals are according to IUPAC, the collection of seventeen Chemical elements in the Periodic table, namely The most common uses of phosphors are in CRT displays and fluorescent lights. The cathode ray tube (CRT is a Vacuum tube containing an Electron gun (a source of electrons and a Fluorescent screen with internal or A fluorescent lamp or fluorescent tube is a Gas-discharge lamp that uses Electricity to excite mercury Vapor. CRT phosphors were standardized beginning around World War II and designated by the letter "P" followed by a number. World War II, or the Second World War, (often abbreviated WWII) was a global military conflict which involved a majority of the world's nations, including

Contents

Materials

Phosphors are usually made from a suitable host material, to which an activator is added. The best known type is a copper-activated zinc sulfide and the silver-activated zinc sulfide (zinc sulfide silver).

The host materials are typically oxides, sulfides, selenides, halides or silicates of zinc, cadmium, manganese, aluminum, silicon, or various rare earth metals. An oxide is a Chemical compound containing at least one Oxygen atom as well as at least one other element The term sulfide ( sulphide in British English) refers to several types of Chemical compounds containing Sulfur in its lowest Oxidation The selenide Ion is Se2&minus A selenide is a chemical compound in which Selenium serves as an Anion with Oxidation number A halide is a Binary compound, of which one part is a Halogen Atom and the other part is an element or radical that is less For the Artificial intelligence Androids of the 1990s Science fiction series Space Above and Beyond, see Silicate (AI Zinc (ˈzɪŋk from Zink is a Metallic Chemical element with the symbol Zn and Atomic number 30 Cadmium (ˈkædmiəm is a Chemical element with the symbol Cd and Atomic number 48 Manganese (ˈmæŋgəniːz is a Chemical element, designated by the symbol Mn. WikipediaNaming Silicon (ˈsɪlɪkən or /ˈsɪlɪkɒn/ silicium is the Chemical element that has the symbol Si and Atomic number 14 Rare earth elements and rare earth metals are according to IUPAC, the collection of seventeen Chemical elements in the Periodic table, namely The activators prolong the emission time (afterglow). In turn, other materials (eg. nickel) can be used to quench the afterglow and shorten the decay part of the phosphor emission characteristics. Nickel (ˈnɪkəl is a metallic Chemical element with the symbol Ni and Atomic number 28

Glow-in-the-dark toys

Spectra of constituent blue, green and red phosphors in a common cathode ray tube.
Spectra of constituent blue, green and red phosphors in a common cathode ray tube. The cathode ray tube (CRT is a Vacuum tube containing an Electron gun (a source of electrons and a Fluorescent screen with internal or

In these applications, the phosphor is directly added to the plastic from which the toys are molded, or mixed with a binder for use as paints. Plastic is the general common term for a wide range of synthetic or semisynthetic organic solid materials suitable for the manufacture of industrial products

ZnS:Cu phosphor is used in glow-in-the-dark cosmetic creams frequently used for Halloween make-ups. Halloween, or Hallowe’en, is a Holiday celebrated on the night of October 31. [2]

Generally, the persistence of the phosphor increases as the wavelength increases. .

See also lightstick for chemiluminescence-based glowing items. A glow stick is a single-use translucent Plastic tube containing isolated substances which when combined are capable of producing Light through a Chemical reaction Chemiluminescence (sometimes " chemoluminescence " is the emission of Light ( Luminescence) with limited emission of heat as the result of a chemical

Radioactive light sources

Mixtures of zinc sulfide with radioactive materials, where the phosphor was excited by the alpha- and beta-decaying isotopes, were used to paint dials of watches and instruments. Radioactive decay is the process in which an unstable Atomic nucleus loses energy by emitting ionizing particles and Radiation. A watch is a timepiece that is made to be worn on a person The term now usually refers to a wristwatch, which is worn on the wrist with a strap or Bracelet. The formula used on watch dials between 1913 and 1950 was a mix of radium-228 and radium-226 with a scintillator made of zinc sulfide and silver (ZnS:Ag). Radium (ˈreɪdiəm is a radioactive Chemical element which has the symbol Ra and Atomic number 88 A scintillator is a substance that absorbs high-energy (ie Ionizing) electromagnetic or charged Particle radiation then in response fluoresces [3] However, zinc sulfide undergoes degradation of its crystal lattice structure, leading to gradual loss of brightness significantly faster than the depletion of radium.

The ZnS:Ag phosphor yields greenish glow. It is not suitable to be used in layers thicker than 25 mg/cm², as the self-absorption of the light then becomes a problem. ZnS:Ag coated screens were used by Ernest Rutherford in his experiments discovering atomic nucleus. Ernest Rutherford 1st Baron Rutherford of Nelson, OM, PC, FRS (30 August 1871 – 19 October 1937 was a New Zealand Physicist The nucleus of an Atom is the very dense region consisting of Nucleons ( Protons and Neutrons, at the center of an atom

Copper-activated zinc sulfide (ZnS:Cu) is the most common phosphor used. It yields blue-green light.

Copper and magnesium activated zinc sulfide (ZnS:Cu,Mg) yields yellow-orange light.

Trasers are light producing devices composed of a sealed borosilicate glass tube with inner coat of a phosphor, filled with tritium. Self-powered lighting is a generic term describing devices that emit light continuously without an external power source Borosilicate glass is a type of Glass with the main glass-forming constituents Silica and Boron oxide. Tritium (ˈtɹɪtiəm symbol or, also known as Hydrogen-3) is a radioactive Isotope of Hydrogen. Betalights use tritium as energy source as well. Self-powered lighting is a generic term describing devices that emit light continuously without an external power source

Electroluminescence

Main article: Electroluminescence

Electroluminescence can be exploited in light sources. Electroluminescence (EL is an Optical phenomenon and Electrical phenomenon in which a material emits light in response to an Electric current passed through Electroluminescence (EL is an Optical phenomenon and Electrical phenomenon in which a material emits light in response to an Electric current passed through Such sources typically emit from a large area, which makes them suitable for backlights of eg. LCD displays. The excitation of the phosphor is usually achieved by application of high-intensity electric field, usually with suitable frequency. In Physics, the space surrounding an Electric charge or in the presence of a time-varying Magnetic field has a property called an electric field (that can Current electroluminescent light sources tend to degrade with use, resulting in their relatively short operation lifetimes.

Phosphorwhite in powder
Phosphorwhite in powder

Indium tin oxide (ITO, also known under trade name IndiGlo) composite is used in some Timex watches, though as the electrode material, not as a phosphor itself. Uses ITO is mainly used to make transparent conductive coatings for Liquid crystal displays Flat panel displays Plasma displays touch panels "Californeon" is another trade name of an electroluminescent material, used in electroluminescent light strips.

See also a history of electroluminescent displays.

White LEDs

White light-emitting diodes are usually blue InGaN LEDs with a coating of a suitable material. Indium gallium nitride ( InGaN, x1-x is a Semiconductor material made of a mix of Gallium nitride (GaN and Indium nitride Cerium(III)-doped YAG (YAG:Ce3+, or Y3Al5O12:Ce3+) is often used; it absorbs the light from the blue LED and emits in a broad range from greenish to reddish, with most of output in yellow. Cerium (ˈsɪəriəm is a Chemical element with the symbol Ce and Atomic number 58 YAG redirects here For the IATA airport code see Fort Frances Municipal Airport. The pale yellow emission of the Ce3+:YAG can be tuned by substituting the cerium with other rare earth elements such as terbium and gadolinium and can even be further adjusted by substituting some or all of the aluminium in the YAG with gallium. Terbium (ˈtɝbiəm is a Chemical element with the symbol Tb and Atomic number 65 Gadolinium (ˌgædəˈlɪniəm is a Chemical element that has the symbol Gd and Atomic number 64 However, this process is not one of phosphorescence. The yellow light is produced by a process known as scintillation, the complete absence of an afterglow being one of the characteristics of the process.

White LEDs can also be made by coating near ultraviolet (NUV) emitting LEDs with a mixture of high efficiency europium based red and blue emitting phosphors plus green emitting copper and aluminium doped zinc sulfide (ZnS:Cu,Al). Europium (jʊˈroʊpiəm is a Chemical element with the symbol Eu and Atomic number 63 This is a method analogous to the way fluorescent lamps work. A fluorescent lamp or fluorescent tube is a Gas-discharge lamp that uses Electricity to excite mercury Vapor.

Cathode ray tubes

Cathode-ray tubes produce signal-generated light patterns in a (typically) round or rectangular format. The cathode ray tube (CRT is a Vacuum tube containing an Electron gun (a source of electrons and a Fluorescent screen with internal or Bulky CRTs were used in the black-and-white household television ("TV") sets that became popular in the 1950s, as well as first-generation, tube-based color TVs, and most earlier computer monitors. Television ( TV) is a widely used Telecommunication medium for sending ( Broadcasting) and receiving moving Images, either monochromatic The 1950s Decade refers to the years of 1950 to 1959 inclusive CRTs have also been widely used in scientific and engineering instrumentation, such as oscilloscopes, usually with a single phosphor color, typically green. An oscilloscope (commonly abbreviated to scope or O-scope) is a type of Electronic test equipment that allows signal Voltages to be viewed

White (in black-and-white): The mix of zinc cadmium sulfide and zinc sulfide silver, the ZnS:Ag+(Zn,Cd)S:Ag is the white P4 phosphor used in black and white television CRTs. Television ( TV) is a widely used Telecommunication medium for sending ( Broadcasting) and receiving moving Images, either monochromatic

Red: Yttrium oxide-sulfide activated with europium is used as the red phosphor in color CRTs. Yttrium (ˈɪtriəm is a Chemical element with symbol Y and Atomic number 39 An oxide is a Chemical compound containing at least one Oxygen atom as well as at least one other element The term sulfide ( sulphide in British English) refers to several types of Chemical compounds containing Sulfur in its lowest Oxidation Europium (jʊˈroʊpiəm is a Chemical element with the symbol Eu and Atomic number 63 The development of color TVs took a long time due to the long search for a red phosphor.

Yellow: When mixed with cadmium sulfide, the resulting zinc cadmium sulfide (Zn,Cd)S:Ag, provides strong yellow light. Cadmium sulfide is a chemical compound with the formula CdS. Cadmium sulfide is yellow in colour and is a semiconductor

Green: Combination of zinc sulfide with copper, the P31 phosphor or ZnS:Cu, provides green light peaking at 531 nm, with long glow. Copper (ˈkɒpɚ is a Chemical element with the symbol Cu (cuprum and Atomic number 29

Blue: Combination of zinc sulfide with few ppm of silver, the ZnS:Ag, when excited by electrons, provides strong blue glow with maximum at 450 nm, with short afterglow with 200 nanosecond duration. Silver (ˈsɪlvɚ is a Chemical element with the symbol " Ag " (argentum from the Ancient Greek: ἀργήντος - argēntos gen It is known as the P22B phosphor. [4] This material, zinc sulfide silver, is still one of the most efficient phosphors in cathode ray tubes. The cathode ray tube (CRT is a Vacuum tube containing an Electron gun (a source of electrons and a Fluorescent screen with internal or It is used as a blue phosphor in color CRTs.

The phosphors are usually poor electrical conductors. This may lead to deposition of residual charge on the screen, effectively decreasing the energy of the impacting electrons due to electrostatic repulsion (an effect known as "sticking"). To eliminate this, a thin layer of aluminium is deposited over the phosphors and connected to the conductive layer inside the tube. This layer also reflects the phosphor light to the desired direction, and protects the phosphor from ion bombardment resulting from an imperfect vacuum.

Fluorescent lamps

Various

Some other phosphors commercially available, for use as X-ray screens, neutron detectors, alpha-particle scintillators, etc, are:

See also

External links

Sodium iodide is a white Crystalline Salt with Chemical formula Na[[Iodine I]] used in radiation detection treatment of Iodine deficiency Caesium iodide (CsI is an Ionic compound often used as the input Phosphor of an X-ray image intensifier tube found in Fluoroscopy equipment Lithium fluoride is a Chemical compound of Lithium and Fluorine. Zinc sulfide (or zinc sulphide is a Chemical compound with the formula Zn[[Sulfur S]] The neutron temperature, also called the neutron energy, indicates a free neutron's Kinetic energy, usually given in Electron volts The term This article is a discussion of neutrons in general For the specific case of a neutron found outside the nucleus see Free neutron. Photoluminescence (abbreviated as PL) is a process in which a substance absorbs Photons (electromagnetic radiation and then re-radiates photons Cathodoluminescence is an optical and electrical Phenomenon whereby a beam of Electrons is generated by an Electron gun (e A laser is a device that emits Light ( Electromagnetic radiation) through a process called Stimulated emission.

Dictionary

phosphor

-noun

  1. (chemistry) Any of various compounds of transition metals or of rare earths that exhibits phosphorescence.

Phosphor

-proper noun

  1. alternative name of Phosphorus, the morning star
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